Sr,Nd,Pb and trace element systematics of the New Caledonia harzburgites:Tracking source depletion and contamination processes in a SSZ setting     

Arianna Secchiari  Alessandra Montanini  Delphine Bosch  Patrizia Macera  Dominique Cluzel 《地学前缘(英文版)》2020,11(1):37-55

The New Caledonia ophiolite(Peridotite Nappe)consists primarily of harzburgites,locally overlain by mafic-ultramafic cumulates,and minor spinel and plagioclase lherzolites.In this study,a comprehensive geochemical data set(major and trace element,Sr-Nd-Pb isotopes)has been obtained on a new set of fresh harzburgites in order to track the processes recorded by this mantle section and its evolution.The studied harzburgites are low-strain tectonites showing porphyroclastic textures,locally grading into protomylonitic textures.They exhibit a refractory nature,as attested by the notable absence of primary clinopyroxene,very high Fo content of olivine(91-93 mol.%),high Mg#of orthopyroxene(0.91-0.93)and high Cr#of spinel(0.44-0.71).The harzburgites are characterised by remarkably low REE concentrations(<0.1 chondritic values)and display"U-shaped"profiles,with steeply sloping HREE(DyN/YbN=0.07-0.16)and fractionated LREE-MREE segments(LaN/SmN=2.1-8.3),in the range of modern fore-arc peridotites.Geochemical modelling shows that the HREE composition of the harzburgites can be reproduced by multi-stage melting including a first phase of melt depletion in dry conditions(15%fractional melting),followed by hydrous melting in a subduction zone setting(up to 15%-18%).However,melting models fail to explain the enrichments observed for some FME(i.e.Ba,Sr,Pb),LREE-MREE and Zr-Hf.These enrichments,coupled with the frequent occurrence of thin,undeformed films of Al2 O3,and CaO-poor orthopyroxene(Al2O3=0.88-1.53 wt.%,CaO=0.31-0.56 wt.%)and clinopyroxene with low Na2 O(0.03-0.16 wt.%),Al2 O3(0.66-1.35 wt.%)and TiO2(0.04-0.10 wt.%)contents,point to FME addition during fluid-assisted melting followed by late stage metasomatism most likely operated by subductionrelated melts with a depleted trace element signature.Nd isotopic ratios range from unradiogenic to radiogenic(-0.80<εNdi≤+13.32)and negatively correlate with Sr isotopes(0.70257≤87Sr/86Sr≤0.70770).Pb isotopes cover a wide range,trending from DMM toward enriched,sediment-like,compositions.We interpret the geochemical signature displayed by the New Caledonia harzburgites as reflecting the evolution of a highly depleted fore-arc mantle wedge variably modified by different fluid and melt inputs during Eocene subduction.  相似文献   

BaMn[CO3]2 – a previously unrecognized double carbonate in low-temperature environments: Structural,spectroscopic, and textural tools for future identification     

Michael E. Böttcher  Herta S. Effenberger  Peer-Lennart Gehlken  Georg H. Grathoff  Burkhard C. Schmidt  Patrizia Geprägs  Rainer Bahlo  Olaf Dellwig  Thomas Leipe  Vera Winde  André Deutschmann  Alexander Stark  David Gallego-Torres  Francisca Martinez-Ruiz 《Chemie der Erde / Geochemistry》2012,72(1):85-89

Following a tentative evidence for the occurrence of low-temperature barium manganese(II) carbonates in brackish sediments of the Baltic Sea, a stoichiometric double carbonate, BaMn[CO₃]₂, was synthesized from aqueous solutions at ambient temperature for the first time. Here we report the results of a multi-method approach, including scanning electron microscopy (SEM–EDX) investigations, the chemical composition, and, in particular, the diagnostic powder X-ray diffraction pattern, as well as diagnostic parts of the FT infrared absorption and Raman spectra for future identification of this new carbonate in low-temperature environments, like brackish sediments.  相似文献   

Ecology of active rock glaciers and surrounding landforms: climate,soil, plants and arthropods     

Duccio Tampucci  Mauro Gobbi  Giuseppe Marano  Patrizia Boracchi  Giacomo Boffa  Francesco Ballarin  Paolo Pantini  Roberto Seppi  Chiara Compostella  Marco Caccianiga 《Boreas: An International Journal of Quaternary Research》2017,46(2):185-198

Active rock glaciers are periglacial landforms consisting of coarse debris with interstitial ice or ice‐core. Recent studies showed that such landforms are able to support plant and arthropod life and could act as warm‐stage refugia for cold‐adapted species due to their microclimate features and thermal inertia. However, integrated research comparing active rock glaciers with surrounding landforms to outline their ecological peculiarities is still scarce. We analysed the abiotic (ground surface temperature and humidity, soil physical and chemical parameters) and biotic (plant and arthropod communities) features of two Alpine active rock glaciers with contrasting lithology (silicate and carbonate), and compared them with the surrounding iceless landforms as reference sites (stable slopes and active scree slopes). Our data show remarkable differences between stable slopes and unstable landforms as a whole, while few differences occur between active scree slopes and active rock glaciers: such landforms show similar soil features but different ground surface temperatures (lower on active rock glaciers) and different occurrence of cold‐adapted species (more frequent/abundant on active rock glaciers). Both plant and arthropod species distributions depend mainly on the geographical context as a function of soil pH and on the contrast between stable slopes and unstable landforms as a function of the coarse debris fraction and organic matter content, while the few differences between active scree slopes and active rock glaciers can probably be attributed to microclimate. The role of active rock glaciers as potential warm‐stage refugia for cold‐adapted species is supported by our data; however, at least in the European Alps, their role in this may be less important than that of debris‐covered glaciers, which are able to host cold‐adapted species even below the climatic tree line.  相似文献   

A modelling approach to assessing variations of total suspended solids (tss) mass fluxes during storm events          下载免费PDF全文

Patrizia Piro  Marco Carbone 《水文研究》2014,28(4):2419-2426

Connections between the catchment hydrology and accumulation, washoff and transport of pollutants in wet weather greatly affect the management of urban drainage and its wet‐weather effluents. In recent years, the concept of the first flush has gained on prominence and was further developed for analyzing the interaction between the hydrology and transport of runoff pollutants. One of the most important definitions of the first flush can be derived from the analysis of the m(v) curves (i.e. the curves in which the normalized cumulative pollutant mass is plotted vs the normalized cumulative runoff volume). Indeed the m(v) curves, indicating the distribution of pollutant mass versus volume in wet‐weather flow (WWF) discharges, are commonly used for comparing pollutant discharges for different rainfall events and catchments. In this study, the m(v) curves were used to define the concepts of flow‐limited and mass‐limited WWF events. These two different behaviours have been analysed for rainfall/runoff events observed in the urbanized part of the Liguori catchment in Cosenza (Italy). In order to advance the understanding of the intra‐event variability of m(v) curves, the mathematical rainfall/runoff model Storm Water Management Model of the US Environmental Protection Agency (SWMM) was calibrated for eight observed rainfall/runoff events and the differences between observed and simulated m(v) curves were analysed. The results showed a good correlation between the observed and simulated m(v) curves, and this finding offers further benefits in SWMM model calibration. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Vertical crustal motions from differential tide gauge observations and satellite altimetry in southern Italy     

Carla Braitenberg  Patrizia MarianiLavinia Tunini  Barbara GrilloIldikò Nagy 《Journal of Geodynamics》2011

Our goal is to determine vertical crustal movement rates from tide gauge and satellite altimetry measurements. Tide gauges measure sea level, but as they are fixed to the crust, they sense both sea surface height variations and vertical crustal movements. The differential sea level rates of sufficiently nearby stations are a good means to determine differential crustal movement rates, when sea level height variations can be assumed to be homogeneous. Satellite altimetric measurements determine sea surface height variations directly and can be used to separate the crustal signal from the sea surface height variations in tide gauge measurements. The correction of the tide gauge sea level rates for the sea surface height contribution requires collocation of the satellite pass and the tide gauge station. We show that even if this is not the case, the satellite altimetric observations enable correction of differential tide gauge rates for the effects of sea surface rate inhomogeneities.  相似文献   

A spatter-forming, large-scale paroxysm at Stromboli Volcano (Aeolian Islands, Italy): insight into magma evolution and eruption dynamics     

Sonia La Felice  Patrizia Landi 《Bulletin of Volcanology》2011,73(9):1393-1406

This study focuses on a pyroclastic sequence related to a large-scale paroxysm that occurred during the seventeenth century ad and which can be considered one of the most powerful and hazardous explosive events at the volcano in the past few centuries. Paroxysms are energetic, short-lived explosions which sporadically interrupt normal Strombolian activity at Stromboli and commonly erupt a deep-derived, volatile-rich crystal-poor high-potassium basalt (“low porphyricity” (LP)), together with a shallow, degassed crystal-rich high-potassium to shoshonitic basalt (“high porphyricity” (HP)), which feed normal activity at the volcano. The studied deposit, crops out along the flanks of Sciara del Fuoco and, from base to top, consists of: (1) a layer of HP and LP ash and lapilli; (2) an unwelded layer of coarse HP lapilli and flattened dark scoriae; (3) weakly welded spatter made up of dense HP pyroclasts at the base, overlain by strongly vesicular LP clasts. The textural and chemical zoning of minerals and the glass chemistry of the LP products record repeated mafic recharge events, mixing with an old mushy body and episodes of rapid crystallization due to sudden degassing. Collapse of a foam layer originated by deep degassing probably triggered this large-scale, spatter-forming paroxysm. Decompression induced rapid degassing and vesiculation of the deep volatile-rich magma. The rapid ascent of the foamy magma blob pushed the shallow HP magma out and finally produced a fire fountain that emplaced the LP portion of the spatter.  相似文献   

Flounder growth and production as indicators of the nursery value of marsh habitats in a Mediterranean lagoon     

Anita Franco  Riccardo Fiorin  Matteo Zucchetta  Patrizia Torricelli  Piero Franzoi 《Journal of Sea Research》2010,64(4):457-464

Estuarine marshes are known as suitable nursery areas for many marine migrant fishes, such as flounder. The potential nursery value of such habitats was investigated in the Venice lagoon, by using growth and production of 0-group flounder as indicators. Size–frequency distribution analysis was performed on fish samples collected fortnightly, from March 2004 to June 2005, in two marsh sites, Dese and Tessera, differing in their origin and environmental conditions. Samples were mostly composed of juvenile individuals, belonging to 0- and 1-group cohorts (the latter being present in Tessera only). A higher total production, either annual or monthly, and faster growth of 0-group flounder was observed in Dese, associated to a higher ecological performance of 0-group individuals in this site, as indicated by the higher P:B ratio values. Dese is a site located in a marsh complex characterized by the relevant influence of a nearby river, and the observed higher potential nursery value of this marsh area with respect to the other is discussed in the light of the higher trophic status and other environmental conditions in this site. The production results were also compared to those from other estuarine environments commonly acknowledged as important nurseries for European flounder.  相似文献   

Multi-criteria, multi-objective and uncertainty analysis for agro-energy spatial modelling     

Patrizia Tenerelli  Steve Carver 《Applied geography (Sevenoaks, England)》2012,32(2):724-736

The worldwide increase in the use of biomass as a Renewable Energy Source raises the issue of introducing crops dedicated to energy production into rural landscapes. The purpose of this paper is to set-up a GIS based multi-criteria approach to assess a range of possibilities for perennial energy crops conversion. The presented method was implemented at the regional level in the Yorkshire and the Humber Region in Northern UK. The first phase of the study aims to set-up a land capability model for the specific purpose of assessing the potential of different typologies of perennial energy crops, on the basis of specific pedo-climatic and topographic factors. The model output illustrates a range of potentials for energy crop conversion that can be explored in the given landscape. In the second phase a uncertainty analysis of the land capability model was performed through a simulation approach in order to interpret the influence of assumptions and uncertainty on input data and model parameters. The last phase of the study allows allocating the energy crop conversion area according to specific environmental constraints, nature protection targets, food production priorities and land capability values. The land allocation output gives a rather restrictive energy crop penetration scenario, where more than half of the conversion area is allocated to cropping systems with low land degradation potential. This scenario represents a preliminary regional analysis of the energy crop potential in terms of theoretically available conversion areas. The final results also show that the areas with highest environmental risks correspond to the areas with both the lowest suitability for energy crop cultivation and the highest model uncertainty.  相似文献   

Dynamics of magma mixing and degassing recorded in plagioclase at Stromboli (Aeolian Archipelago,Italy)     

Patrizia?LandiEmail author  Nicole?Métrich  Antonella?Bertagnini  Mauro?Rosi 《Contributions to Mineralogy and Petrology》2004,147(5):629-631

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Lithological control on thrust-related deformation in the Sassa-Guardistallo Basin (Northern Apennines hinterland, Italy)     

Andrea Cerrina Feroni  Marco Bonini†  Patrizia Martinelli  Giovanna Moratti†  Federico Sani‡  Domenico Montanari†‡  Chiara Del Ventisette†‡ 《Basin Research》2006,18(3):301-321

The Sassa‐Guardistallo Basin (SGB) is located close to the Tyrrhenian Sea and represents one of the most internal Neogene–Quaternary hinterland basins of the Northern Apennines fold‐and‐thrust belt. Its sedimentary succession consists of ca. 400‐m‐thick Late Tortonian–Messinian continental – largely conglomeratic – units overstepping a mainly shaly substratum (Palombini Shales) and overlain by Late Messinian evaporites and marine to continental Pliocene–Pleistocene sediments. This stratigraphic succession can be approximated to a composite rheological multilayer that dictated the style of basin deformation. Detailed geological mapping and structural analysis revealed that basin deposits were affected by compressional deformations that can be found both at map and outcrop scales. Decametric splay thrusts emanating from the substratum–conglomerate interface locally double the continental succession and are bounded by a roof thrust along the Late Messinian evaporite décollement, defining a deformation pattern consistent with a duplex‐like structure. The time–space structural evolution of the basin inferred from the fieldwork was addressed and tested by analogue modelling that approximated the rheological stratification of the study area to a layered brittle–ductile system. The model results support the hypothesis that the evolution of the thrust system affecting the SGB started as an early floor imbricate fan thrust system that successively evolved to a duplex structure as the link thrusts propagated into the upper décollement layer that resulted from the deposition of the Late Messinian evaporites. Models display many structural features that may be compared with the natural prototype, and highlight the importance of syntectonic sedimentation in the development and evolution of tectonic structures. The results of this study retain relevant implications for the Neogene evolution of the Tyrrhenian Basin–Northern Apennines system. This study also supports that combining between field structural analyses and analogue modelling can give useful hints into the evolutionary history of tectonically complex areas.  相似文献